Lignocellulosic feedstock evaluation (sugarcane bagasse and coconut shells) for ethanol production as a potential refinery fuel additive

Authors

  • Pedro Gelson Morais Jean Piaget University of Angola image/svg+xml , Centro de Pesquisa e Desenvolvimento da Sonangol, S.A. image/svg+xml Author
  • Adilson Venâncio Martins Jean Piaget University of Angola image/svg+xml Author
  • Onésimo Sebastião Fula Francisco Jean Piaget University of Angola image/svg+xml Author
  • Elvis Napoleão Queto Cardoso Jean Piaget University of Angola image/svg+xml Translator
  • Sónia Marinela da Silva Rêgo de Sousa Paim Author
  • Kavuanda Francisco Jean Piaget University of Angola image/svg+xml Author
  • Lúcia Rafael Funda Jean Piaget University of Angola image/svg+xml Author
  • Jacinta Pinto António Jean Piaget University of Angola image/svg+xml Author
  • Vlademir Pereira Petroangola Author
  • Samuel Carlos Victorino Jean Piaget University of Angola image/svg+xml Author

Keywords:

Potential; Lignocellulosic waste; Sugarcane bagasse; Coconut husks; Refining additives

Abstract

This study evaluated the potential of sugarcane bagasse and coconut shells as feedstocks for producing second-generation ethanol intended as a sustainable oxygenate additive in refinery gasoline. Using a rigorous methodology that included physicochemical characterization of the biomass, acid hydrolysis and fermentation with Saccharomyces cerevisiae, and robust statistical analysis, the results demonstrated the technical feasibility of both residues. Coconut shells stood out for their higher calorific value (16.44 MJ/kg) and significantly higher fermentation yield (90.42%) compared to bagasse (12.6 MJ/kg and 83.20%). Both ethanol products had alcohol contents above 93% v/v, complete combustion with no detectable residues, and, critically, extremely low sulfur content (<0.12%). Statistical analysis using Student's t-test for independent samples (α = 0.05) confirmed a significant difference in fermentation yields between the two biomasses (p = 0.012). However, the low final ethanol titers (≈6 g/L) obtained under the current non-optimized protocol remain a critical bottleneck. It is concluded that while both residues are technically feasible as feedstocks, substantial process optimization, particularly in pretreatment and hydrolysis, is required before their ethanol can be considered for industrial application. The extremely low sulfur content (<0.12%) supports their potential for producing cleaner fuels within a circular economic framework. Recovering these wastes through co-processing in refineries is an effective strategy to promote the circular economy, improve fossil fuel quality (by increasing octane ratings), and contribute to the decarbonization of the transport sector.

Author Biographies

  • Pedro Gelson Morais, Jean Piaget University of Angola, Centro de Pesquisa e Desenvolvimento da Sonangol, S.A.

    PhD Candidate in Chemical Engineering at PPGEQ/ Federal Uberlândia, University.Assistant Lecturer in Petroleum Refining Technology and Product Analysis, Obtained in Petroleum Refineries, Faculty of Science and Technology, Jean Piaget University of Angola, Viana, Kapalanca, Luanda, Angola Researcher in industrial processes, modeling and optimization of refinery processes end products, biofuel production end Transition Energy in Sonangol Research and Development Center, SA, Sumbe, Cuanza Sul, Angola

  • Adilson Venâncio Martins, Jean Piaget University of Angola

    Petroleum Refining Engineer sfrom UJPA and Research assistant in the area of ​​biofuel production for the integration of co-processing routes in oil refineries at the Faculty of Science and Technology, Jean Piaget University of Angola, Viana, Kapalanca, Luanda, Angola.

  • Onésimo Sebastião Fula Francisco, Jean Piaget University of Angola

    Petroleum Refining Engineer from UJPA and Research assistant in the area of ​​biofuel production for the integration of co-processing routes in oil refineries at the Faculty of Science and Technology, Jean Piaget University of Angola, Viana, Kapalanca, Luanda, Angola

  • Elvis Napoleão Queto Cardoso, Jean Piaget University of Angola

    Petroleum Refining Engineer from UJPA and Research assistant in the area of ​​biofuel production for the integration of co-processing routes in oil refineries, Industrial Sustainability and Energy Transition at the Faculty of Science and Technology, Jean Piaget University of Angola, Viana, Kapalanca, Luanda, Angola.

  • Sónia Marinela da Silva Rêgo de Sousa Paim
      Master's degree in Organizational Psychology, Bachelor's degree in Economics and Management from UJPA, and Assistant Professor in Business Administration, Economics and Management, and Project Manager of scientific research in the area of ​​Science and Technology at the Faculty of Sciences and Technology, Jean Piaget University of Angola, Viana, Kapalanca, Luanda, Angola.
  • Kavuanda Francisco, Jean Piaget University of Angola

    Petroleum Research and Production Engineer from UJPA and Assistant Lecturer in Reservoir Engineering and Researcher in the area of ​​Computational Simulation and Modeling of Petroleum Operations at the Faculty of Science and Technology, Jean Piaget University of Angola, Viana, Kapalanca, Luanda, Angola

  • Lúcia Rafael Funda, Jean Piaget University of Angola
    Petroleum Research and Production Engineer from UJPA and Assistant Professor of Statistics and Data Analysis, Natural Gas Engineering and Petroleum Engineering Design, and Researcher in the area of ​​Petroleum Production Engineering Processes, Faculty of Science and Technology, Jean Piaget University of Angola, Viana, Kapalanca, Luanda, Angola
  • Jacinta Pinto António, Jean Piaget University of Angola

    Petroleum Refining Engineer stutedent from UJPA and intern research in the area of ​​biofuel production for the integration of co-processing routes in oil refineries at the Faculty of Science and Technology of the Jean Piaget University of Angola.

  • Vlademir Pereira, Petroangola
    Petroleum Exploration and Production Engineer from ISPK, Strategy Consultant, Oil and Gas Market Analyst at Petroangola, and Opinion Leader.      
  • Samuel Carlos Victorino, Jean Piaget University of Angola

    PhD in Agricultural Sciences, specializing in Pedology, from the Faculty of Agricultural Sciences at the Christian Albrechts University of Kiel – Germany; Full Professor of Biostatistics in the General Medicine course at the Faculty of Health Sciences of UniPiaget and in the Biology course at the Faculty of Sciences of Agostino Neto University; researcher in the application of statistical methods in various fields of knowledge.

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Published

2026-07-04

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